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Basics of Elastomeric Seal Design

Basics of Elastomeric Seal Design

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Controlling Our Water Systems, Part II

Controlling Our Water Systems, Part II

To better understand the actuators and c...

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Controlling Our Water Systems

Actuators and controls are a critical pr...

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Industry Headlines

Crane Co. Reports Second Quarter 2016 Results

19 HOURS AGO

Crane Co. reported second quarter 2016 GAAP earnings of $1.15 per diluted share, compared to $0.95 per share in the second quarter of 2015. Excluding Special Items, second quarter 2016 earnings per diluted share were $1.21, compared to $1.06 per share in the second quarter of 2015.

Second quarter 2016 ...

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Emerson Exploring Acquisition of Pentair Valves & Controls

1 DAY AGO

Reuters UK has spoken to sources that confirm Emerson has made an offer to acquire Pentair Valves & Controls. Pentair Plc added the Valves & Controls division after its merger with Tyco Flow Control in 2012.

“Pentair has received offers for the valves and controls business from companies o...

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LNG’s Surge from Decade-Low Seen Fizzling as Supply Ramps Up

-1 DAYS AGO

“LNG’s surge is running out of gas. Liquefied natural gas in Asia, which was in such over-supply that prices in Japan fell to a decade-low in April, has risen by almost half in the past three months as production outages stifled supply, demand rose in places like China and India and a co...

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Chemical Activity Barometer Grows for Fourth Consecutive Month

20 HOURS AGO

The Chemical Activity Barometer (CAB) expanded 0.4% in July following a revised 0.7% increase in June, 0.8% increase in May and 0.6% increase in April. All data is measured on a three-month moving average. Accounting for adjustments, the CAB remains up 2.6% over this time last year, an improvement ove...

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U.S. Durable Goods Orders Down 4% in June

-1 DAYS AGO

New orders for manufactured durable goods in June decreased $9.3 billion or 4.0% to $219.8 billion, the U.S. Department of Commerce announced. This decrease , down two consecutive months, followed a 2.8% May decrease. Excluding transportation, new orders decreased 0.5%. Excluding defense, new orders d...

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Sharpest Rise in U.S. Manufacturing Production Since November

1 DAY AGO

July data signaled a further rebound in business conditions across the U.S. manufacturing sector, led by a robust expansion of incoming new work and the fastest upturn in production volumes for eight months. Job creation also strengthened in July, with the latest increase in payroll numbers the fast...

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NACE MR0103 and Duplex Stainless Steels

materials_q_and_a_graphicQ: Why are some suppliers reluctant to produce duplex stainless-steel valves that are compliant with NACE MR0103?

 

A: Duplex stainless steels are those that are chemically balanced to provide a target microstructure of 50% austenite phase and 50% ferrite phase. Duplex stainless-steel valves required to meet NACE MR0103 will almost always be installed in a sour, corrosive, chloride-containing environment, so it is essential the material provides optimized resistance to sulfide stress cracking, chloride stress corrosion cracking, chloride pitting and general corrosion.

 

The task group that created the NACE MR0103 document, “Materials Resistant to Sulfide Stress Cracking in Corrosive Petroleum Refining Environments,” recognized that microstructure is a key factor influencing the properties of duplex stainless steel. They also recognized that the microstructure is influenced strongly by chemistry and by heating and cooling during processing of the material. As a result, NACE MR0103 includes some very stringent requirements for duplex stainless steels, especially with regard to welding. Since most valve bodies (and many bonnets) are produced from castings, welding will be performed. Although most welding will be minor and cosmetic in nature, NACE MR0103 does not distinguish between minor and major weld repairs when it comes to welding requirements for these materials.

During welding, the cooling rates that occur in the weld deposit and in the heat-affected zone (HAZ) can have dramatic effects on the final microstructure. Higher cooling rates tend to promote higher ferrite levels, which are advantageous for chloride stress corrosion cracking resistance but detrimental to sulfide stress cracking resistance and impact resistance. Conversely, slower cooling rates promote lower ferrite levels, which will result in increased sulfide stress cracking resistance and toughness, but reduced chloride stress corrosion cracking resistance, and can allow the formation of harmful second phases that detract from the overall corrosion resistance of the material.

Therefore, successful welding of duplex stainless steels to provide optimum properties is a fine balancing act, which requires careful control of welding parameters that affect the cooling rate of the weldment.

Welding Requirements

In order to achieve the necessary control over cooling rates during welding, NACE MR0103 includes several requirements with regard to qualification of welding procedures:

  1. Each procedure qualification specimen must be hardness surveyed using to 10 kg Vickers hardness scale. The readings must average no more that 310 HV 10, and no individual reading is allowed to exceed 320 HV 10.
  2. The ferrite content must be measured metallographically in the weld deposit and HAZ of each procedure qualification specimen. The measured ferrite content must fall within the 35% to 65% range in all measured locations.
  3. The heat input required per the resulting welding procedure specification must not deviate by more than 10% from the heat input used when producing the procedure qualification specimen(s).
  4. The base metal thickness range qualified by a given procedure specimen of thickness T is 0.8T to 1.2T.

 

Requirements 1 and 2, although they add testing over and above the normal ASME Section IX requirements, are not overly problematic.

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