06222018Fri
Last updateFri, 22 Jun 2018 2pm

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From Cannon Balls to Pressure Seals: Graphite for Sealing

From Cannon Balls to Pressure Seals: Graphite for Sealing

From time to time, we re-publish well-re...

Gaskets Are Not Created Equal

Gaskets Are Not Created Equal

Gaskets are near the bottom of the food ...

Your Valves May Be Weaponized

Your Valves May Be Weaponized

The advent of the Internet of Things (Io...

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Industry Headlines

SVF Flow Controls Joins VMA

Friday, 22 June 2018  |  Chris Guy

This week SVF Flow Controls became a full member of the Valve Manufacturers Association (VMA). This is the fourth new VMA member in 2018 so far.

For over...

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Industry Headlines

SVF Flow Controls Joins VMA

1 HOUR AGO

This week SVF Flow Controls became a full member of the Valve Manufacturers Association (VMA). This is the fourth new VMA member in 2018 so far.

For over 35 years SVF Flow Controls of La Palma, CA has been manufacturing ball valves, actuators and controls for all industrial applications.

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Emerson Wins Global Tank Storage Award

22 HOURS AGO

Emerson’s Rosemount 5900S 2-in-1 Radar Level Gauge has won the Outstanding Terminal Safety Technology Award at the 2018 Global Tank Storage Awards. This award is given to a product or technology that adds an additional layer of safety to the terminal and reduces risk to employees and the surroun...

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U.S. Specialty Chemicals Markets Continue to Gain

22 HOURS AGO

The American Chemistry Council (ACC) reported that U.S. specialty chemicals market volumes continued to gain during the second quarter, increasing 0.5% in May after an upwardly revised 1% gain in April and a 0.4% gain in March. All changes in the data are reported on a three-month moving average (3M...

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Global LNG Trade Growing, Led by Australia and the U.S.

1 DAY AGO

Global trade in liquefied natural gas (LNG) reached 38.2 billion cubic feet per day (Bcf/d) in 2017, a 10% (3.5 Bcf/d) increase from 2016 and the largest annual volume increase since 2010, according to the Annual Report on LNG trade by the International Association of Liquefied Natural Gas Importers...

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Optimism an All-Time High in NAM Survey

1 DAY AGO

In the latest Manufacturers’ Outlook Survey from the National Association of Manufacturers (NAM), it’s clear that businesses continue to experience highly elevated levels of activity as a result of policies like tax reform, with optimism once again breaking records —95.1% of responde...

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Texas Economy Continues to Expand at “Solid Pace”

2 DAYS AGO

The Texas economy is expanding at a solid pace. Employment has grown at a 3.6% annualized rate through May, driven by job gains in the goods-producing sector. Unemployment remains near its historical low, and labor markets are tight. The Dallas Fed’s Texas Business Outlook Surveys (TBOS) suggest...

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NACE MR0103 and Duplex Stainless Steels

materials_q_and_a_graphicQ: Why are some suppliers reluctant to produce duplex stainless-steel valves that are compliant with NACE MR0103?

 

A: Duplex stainless steels are those that are chemically balanced to provide a target microstructure of 50% austenite phase and 50% ferrite phase. Duplex stainless-steel valves required to meet NACE MR0103 will almost always be installed in a sour, corrosive, chloride-containing environment, so it is essential the material provides optimized resistance to sulfide stress cracking, chloride stress corrosion cracking, chloride pitting and general corrosion.

 

The task group that created the NACE MR0103 document, “Materials Resistant to Sulfide Stress Cracking in Corrosive Petroleum Refining Environments,” recognized that microstructure is a key factor influencing the properties of duplex stainless steel. They also recognized that the microstructure is influenced strongly by chemistry and by heating and cooling during processing of the material. As a result, NACE MR0103 includes some very stringent requirements for duplex stainless steels, especially with regard to welding. Since most valve bodies (and many bonnets) are produced from castings, welding will be performed. Although most welding will be minor and cosmetic in nature, NACE MR0103 does not distinguish between minor and major weld repairs when it comes to welding requirements for these materials.

During welding, the cooling rates that occur in the weld deposit and in the heat-affected zone (HAZ) can have dramatic effects on the final microstructure. Higher cooling rates tend to promote higher ferrite levels, which are advantageous for chloride stress corrosion cracking resistance but detrimental to sulfide stress cracking resistance and impact resistance. Conversely, slower cooling rates promote lower ferrite levels, which will result in increased sulfide stress cracking resistance and toughness, but reduced chloride stress corrosion cracking resistance, and can allow the formation of harmful second phases that detract from the overall corrosion resistance of the material.

Therefore, successful welding of duplex stainless steels to provide optimum properties is a fine balancing act, which requires careful control of welding parameters that affect the cooling rate of the weldment.

Welding Requirements

In order to achieve the necessary control over cooling rates during welding, NACE MR0103 includes several requirements with regard to qualification of welding procedures:

  1. Each procedure qualification specimen must be hardness surveyed using to 10 kg Vickers hardness scale. The readings must average no more that 310 HV 10, and no individual reading is allowed to exceed 320 HV 10.
  2. The ferrite content must be measured metallographically in the weld deposit and HAZ of each procedure qualification specimen. The measured ferrite content must fall within the 35% to 65% range in all measured locations.
  3. The heat input required per the resulting welding procedure specification must not deviate by more than 10% from the heat input used when producing the procedure qualification specimen(s).
  4. The base metal thickness range qualified by a given procedure specimen of thickness T is 0.8T to 1.2T.

 

Requirements 1 and 2, although they add testing over and above the normal ASME Section IX requirements, are not overly problematic.

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