06302016Thu
Last updateWed, 29 Jun 2016 5pm

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Fugitive Emissions—Issues and Opportunities

Fugitive Emissions—Issues and Opportunities

Fugitive emissions, ppm, consent decrees...

Problem-Driven Innovation

Problem-Driven Innovation

Developing Alternative Technology to Imp...

Valve Repair Takes Center Stage in Houston

Valve Repair Takes Center Stage in Houston

Attendees gathered June 2-3 in Houston t...

What Internal Best Practices Can Do for Valve Selection

What Internal Best Practices Can Do for Valve Selection

As time goes by, technology moves forwar...

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Industry Headlines

Emerson Selected to Upgrade SE Virginia Wastewater Utility

12 HOURS AGO

Emerson Process Management is replacing an outdated supervisory control and data acquisition (SCADA) system as well as remote terminal units (RTUs) used throughout Hampton Roads Sanitation District’s (HRSD) wastewater collection system. Currently, HRSD serves about 1.7 million people over an are...

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MSS Publishes Revised Standard for High Pressure Knife Gate Valves

1 DAY AGO

The Manufacturers Standardization Society (MSS) announces that recently revised Standard Practice, SP-135-2016, High Pressure Knife Gate Valves, has been approved by the American National Standards Institute (ANSI) as an American National Standard (ANS).

The first edition of MSS SP-135 was published in...

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U.S. Crude Storage Capacity Utilization Rises Even as Capacity Grows

10 HOURS AGO

Weekly U.S. commercial crude oil inventories have increased by more than 71 million barrels (15%) since the end of September, pushing crude oil storage capacity utilization to a near record high of 73% for the week ending June 10.

The U.S. Energy Information Administration (EIA) measures crude oil stor...

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Oil Sands Production Forecast to Grow by Nearly 1M bpd

1 DAY AGO

IHS, in its outlook for Canadian oil sands production through 2025, expects continued growth through the period. IHS anticipates a new phase driven primarily by the expansion of existing facilities with more attractive economics.

Oil sands production is forecast to grow by nearly one million barrels pe...

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Trump Comes Out Against Trade, Draws Pushback

13 HOURS AGO

GOP presidential candidate Donald Trump, speaking Tuesday near Pittsburgh, expressed fierce opposition to free-trade agreements and criticized Hillary Clinton for supporting them. Trump blamed Clinton and her husband for the loss of millions of manufacturing jobs and threatened to pull the U.S. out ...

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Consumer Confidence Climbs to 8-Month High

1 DAY AGO

The Conference Board Consumer Confidence Index, which had decreased in May, improved in June. The Index now stands at 98.0 , up from 92.4 in May. Those stating business conditions are “good” increased slightly from 26.1% to 26.9%, while those saying business conditions are “bad&rdquo...

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Use of Hard Coatings for Valves

What types of coatings are available for valves in severe service abrasion service?
Valves operating in this type of service require enhanced durability and corrosion resistance. The coatings widely used for valves include HVOF, hard chrome and D-gun, all of which provide a hard surface with much better resistance to abrasion compared to uncoated parts.

Do these coating technologies have any limitations?
These traditional coating technologies do have some limitations and undesirable side-effects. The coatings are porous, especially HVOF, which when used with gas requires special sealing to stop gas diffusion through the coating pores. Both HVOF and D-gun coatings contain metal binder, usually cobalt or sometimes nickel or chrome. Most of the binders are prone to corrosion and attacks by aggressive media such as H2S, which is present in sour oil or nitric acid used for cleaning food processing equipment. The binder leaching dramatically increases coating abrasiveness, and seals wear much quicker. HVOF and D-gun coatings can only be applied to external surfaces, are very rough as applied, and require expensive grinding and finishing. Also, hard chrome plating causes significant environmental concerns and will be phased-out in many developed countries.

Are there any alternatives?
Yes, there is a new advanced coating that resolves these problems and is increasingly used in high-performance valves: Hardide is a nano-structured tungsten-carbide coating applied by an innovative low-temperature chemical vapor deposition (CVD). This coating became commercially available four years ago following more than 15 years of research and development. Since then it has been successfully used with valves serving in the oil and gas industry, food processing, cryogenics and for handling aggressive chemicals.

Please explain how Hardide works and describe some of its properties.
Hardide is a pore-free coating that is crystallised on the surface of steel parts in a vacuum furnace filled with a special recipe of mixed reactive gases. The coating is crystallised atom-by-atom from gas phase; the highly mobile reaction products fill pores and defects in the coating as it grows. The porosity measured as the difference between theoretical and actual material density is less than 0.04%, while the coating completely covers the substrate without any through pores starting from less than 1 micron thickness. Absence of porosity is important for gas valves where pores can result in explosive gas leaks.

Hardide coating thickness can vary between 5 and 100 microns. In most valve applications 40 to 60 microns coating is optimal. Typically, the coating increases the life of precipitation-hardened stainless-steel parts in abrasive conditions by a factor of three.

Dispersed tungsten-carbide nano particles give the material enhanced hardness of between 1100 and 1600 Hv, and abrasion resistance is up to 12 times better than hard chrome. Nano-structured materials sometimes show unique toughness, crack and impact-resistance and Hardide-T has proven this by withstanding 3000 microstrain deformations without any damage—this deformation will crack or chip any other thick hard coating.

How is this coating different than sprayed tungsten carbide?
Unlike sprayed tungsten carbide, Hardide does not use cobalt, which can be affected by corrosion. Binder-free Hardide resists attacks of salts, acids, H2S, molten metals and many other aggressive media. This is especially important for the petrochemical industry processing sour oil. The coating is resistant to acids and aggressive media. In fact, its resistance to H2S has been proven by NACE testing. A 17-4 stainless-steel sample coated with Hardide passed the test without any changes in appearance or structure, while an uncoated control sample was broken into two pieces due to sulphide stress cracking effect.

What are some of Hardide’s other features?
The Hardide coating allows use of standard steels in highly corrosive and aggressive environments, opens wider opportunities for the valve design and reduces machining costs.

The CVD process enables the coating of internal and shaped “out of line-of-sight” surfaces of parts made of steel, stainless steel, Monel, Inconel, copper, Stellite and other alloys.

In addition, the Hardide structure permits good quality surface finish and provides anti-galling properties.

Does it have any other applications?
Apart from valves, Hardide has commercial applications for tools in the oil industry and heavy-duty parts for earth-moving equipment, as well as pumps.

What do you see happening with Hardide in the future?
Future developments in Hardide coating technology should allow making coating self-lubricating by inclusion of solid lubricant materials. This will facilitate valve operation, especially for high-pressure valves, as well as permitting use of smaller actuators. VM

Dr.Yuri Zhuk is technical director of Hardide plc (www.hardide.com). In 2003, the company’s headquarters and coating facility were established in Bicester, Oxfordshire in the UK; Hardide Coatings’ first international coatings plant opened in Houston, TX in September 2006. To reach Dr. Zhuk, please email This email address is being protected from spambots. You need JavaScript enabled to view it..

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