08252016Thu
Last updateThu, 25 Aug 2016 4pm

i

Valve Basics Training Helps Fill Industry Skills Gap

Valve Basics Training Helps Fill Industry Skills Gap

One of the most keenly felt needs in tod...

An End-User’s Perspective on Valve Selection and Risk

An End-User’s Perspective on Valve Selection and Risk

I am not a valve expert, although I ofte...

New Test Stamp and More Updates on Pressure Vessel Codes

New Test Stamp and More Updates on Pressure Vessel Codes

A new test organization program and stam...

The Role of Valves in HAZOP Studies

The Role of Valves in HAZOP Studies

Process hazard analysis (PHA) is require...

The Weekly Report

New Products

  • ja-news-2
  • ja-news-3

Industry Headlines

Advertisement
i

Industry Headlines

ValvTechnologies Successfully Completes NUPIC Audit

21 HOURS AGO

ValvTechnologies, Inc. recently achieved NUPIC-approved suppliers list status, upon successful completion of the Nuclear Procurement Issues Committee (NUPIC) audit conducted at the Houston facility. NUPIC members include all domestic U.S. nuclear utilities as well as several international members.

Form...

Readmore

GE Oil & Gas Supporting ONGC’s Exploratory Drilling Campaign in India

23 HOURS AGO

GE Oil & Gas has been awarded a multi-million-dollar frame agreement by Oil and Natural Gas Corporation Limited (ONGC), India’s largest exploration and production company. Under the agreement , GE will provide an estimated 55 subsea wellheads (SG5) over next three years for the operator&rsqu...

Readmore

Chemical Activity Barometer Suggests Accelerated Business Activity

1 DAY AGO

The Chemical Activity Barometer (CAB) expanded 0.4% in August following an upward revision for July. This marks the barometer’s sixth consecutive monthly gain. Accounting for adjustments, the CAB is up 3.2% over this time last year, the strongest year over year growth since January 2015. All d...

Readmore

Innovation Could Lead to Significant Cuts in Chemical Manufacturing Energy Use

1 DAY AGO

Scientists from ExxonMobil and Georgia Tech have developed a new technology that could significantly reduce the amount of energy and emissions associated with manufacturing plastics. If brought to industrial scale, this breakthrough could reduce industry’s global annual carbon dioxide emissions ...

Readmore

Manufacturing Productivity in U.S. Higher Than Other Nations

-1 DAYS AGO

“U.S. productivity unexpectedly declined for a third straight quarter in the three months through June, Labor Department figures showed. On a year-over-year basis, it fell for the first time since 2013,” Bloomberg reports .

But on a more positive note, “the U.S. still blows other natio...

Readmore

Durable Goods Orders Up 4.4%, a Six-Month High

58 MINS AGO

New orders for manufactured durable goods in July increased $9.7 billion or 4.4% to $228.9 billion, the U.S. Commerce Department announced. This increase, up following two consecutive monthly decreases, followed a 4.2% June decrease. Excluding transportation, new orders increased 1.5%. Excluding def...

Readmore

Cobalt-base Alloy 6

materials_q_and_a_graphicQ: Is there a problem using cobalt-base Alloy 6 material in amine applications in refineries and gas treatment plants?

A: This is a very good question, and the answer may be somewhat surprising to many people.

The Materials Q&A column in the Winter 2006 issue of Valve Magazine covered erosion-corrosion issues that can occur when cobalt-base Alloy 6 is used for boiler feedwater service in power plants. To review, boiler feedwater is often treated with amine compounds to deoxygenate the water, which reduces the corrosion rates in the steel piping system. It has been theorized (but not proven) that the presence of the amine compounds somehow prevents the reformation of the oxide passive layer on the Alloy 6 after it has been removed by high-velocity flow impingement. What is not understood is why this only occurs in cobalt alloys and not in other materials (such as austenitic stainless steels) that also rely on an oxide passive layer for corrosion protection.

In refineries, amine compounds are used to absorb unwanted dissolved gases—primarily hydrogen sulfide (H2S)—from liquid hydrocarbons. In natural gas treatment plants, the amine compounds are used to absorb H2S and carbon dioxide (CO2). This process is usually called “sweetening.” The most commonly-used compounds in these applications are the alkanolamines—monoethanolamine (MEA), diethanolamine (DEA) and methyldiethanolamine (MDEA).

The gaseous or liquid hydrocarbon is passed up through an absorber, and the amine fluid is passed in a counterflow direction (i.e., down) through the absorber. The unwanted H2S (and CO2 in the case of natural gas) are absorbed by the amine solution, which results in what is called “rich amine.”

In common systems, the rich amine exits the bottom of the absorber and passes through a rich amine letdown valve, where the pressure drop causes the gases to come out of solution.

Commonly, an amine regenerator valve is present that eventually takes a second pressure drop going into the regenerator. Some outgassing also occurs at this valve, but not to the same extent as is present in the rich amine letdown valve.

The regenerator produces what is called “lean” amine solution, which is then recirculated to the absorber.

Valves controlling the lean amine solution are not susceptible to sulfide stress cracking, and not especially susceptible to corrosion (because no H2S or CO2 is present). However, they do tend to be susceptible to cavitation because of the large pressure drops. These valves are usually supplied with anti-cavitation trim in standard hardened stainless-steel materials.

Valves controlling the rich amine are susceptible to both corrosion and sulfide stress cracking because of the H2S (and CO2 in gas treatment) and are susceptible to erosion damage because of the two-phase flow caused by the outgassing. Therefore, it would be favorable to be able to use a trim material in these valves that is known to be resistant to corrosion and sulfide stress cracking and resistant to erosion by the two-phase flow. Alloy 6 is famous for its resistance to various types of mechanical damage, including cavitation damage, flashing damage (which is similar to the two-phase gas-liquid erosion mechanism encountered here) and galling. It’s also commonly used in applications where sulfide stress cracking is a concern. The big question is, how well does Alloy 6 hold up against corrosion, given the fact that there are amines present in the fluid?

One might theorize that the Alloy 6 would suffer the same erosion-corrosion damage in the rich amine solution as it does in boiler feedwater applications. After all, the amines would scavenge oxygen from the water in the amine solution just as they do in boiler feedwater applications.

Deoxygenation does actually occur. In fact, the theory is this may be the reason for the successful use of 316 stainless steel in gas sweetening systems where temperatures and chloride levels would seem elevated enough to cause chloride stress corrosion cracking (SCC). It is known that as dissolved oxygen decreases, the tendency to suffer chloride SCC decreases. Elimination of dissolved oxygen may be the reason that SCC does not occur.

Despite the fact that theory would indicate a danger of erosion-corrosion for Alloy 6 in these applications, experience has indicated that this material actually works very well. There are literally thousands of control valves installed in rich amine letdown service and amine regenerator service that use Alloy 6 trim components. These valves include Alloy 6 in all the various product forms—solid cast components (UNS R30006), solid wrought components (UNS R30016) and hardface overlays (AWS CoCr-A), and they all work well in practice.

In other words, there is no reason to restrict the use of Alloy 6 trim materials in amine applications in refining and gas treatment systems. Save those restrictions for boiler feedwater applications.


Don Bush is principal materials engineer, Advanced Technology Group, Fisher Division, Emerson Process Management.

  • Latest Post

  • Popular

  • Links

  • Events

Advertisement

Looking for a career in the Valve Industry?

ValveCareers Horiz

To learn more, watch the videos below or visit ValveCareers.com a special initiative of the Valve Manufacturers Association