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Process Instrumentation in Oil and Gas

Process Instrumentation in Oil and Gas

Process instrumentation is an integral p...

Check Valves in LNG Cryogenic Service

Check Valves in LNG Cryogenic Service

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Will Smart Machines Obsolete Human Resources?

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Industry Headlines

U.S. LNG Exports Increased as New Facilities Come Online

Tuesday, 12 December 2017  |  Chris Guy

In August 2017, total U.S. natural gas liquefaction capacity in the lower 48 states increased to 2.8 billion cubic feet per day (Bcf/d) following the ...

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Construction and Mining: Is 2018 The Year for Growth?

Construction and Mining: Is 2018 The Year for Growth?

Tuesday, 12 December 2017  |  Kate Kunkel

While there is a degree of optimism in the mining industry that hasn’t been seen for some years, much uncertainty still exists in this sector. A...

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Industry Headlines

CIRCOR Completes Acquisition of Colfax Fluid Handling

12 HOURS AGO

CIRCOR International has completed the previously announced acquisition of Fluid Handling (FH) from Colfax Corporation for approximately $693 million of cash and newly issued CIRCOR shares, and $150 million related to the assumption of pension plan liabilities linked to the FH business. FH will become...

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Classic Controls Certified by ITT Engineered Valves, REXA

5 DAYS AGO

Classic Controls is now certified by ITT Engineered Valves to repair Skotch brand FM approved and general purpose burner shut-off valves for oil and gas fired systems.

REXA, Inc. has also appointed Classic Controls as its exclusive authorized sales representative in the state of Florida. Classic Contr...

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U.S. LNG Exports Increased as New Facilities Come Online

11 HOURS AGO

In August 2017, total U.S. natural gas liquefaction capacity in the lower 48 states increased to 2.8 billion cubic feet per day (Bcf/d) following the completion of the fourth liquefaction unit at the Sabine Pass liquefied natural gas (LNG) terminal in Louisiana. With increasing liquefaction capacity...

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China to Become Second-Largest LNG Importer

5 DAYS AGO

The world’s no. 1 energy user, China, “is on the verge of passing South Korea to become the No. 2 buyer of LNG behind Japan, as environmental measures and winter heating needs boost demand,” Bloomberg reports .

“Tankers with total capacity of 33.6 million metric tons have visited...

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NAM Survey: Manufacturers’ Optimism Reaches Record High

14 HOURS AGO

The National Association of Manufacturers (NAM) released the results of the Manufacturers’ Outlook Survey for the fourth quarter of 2017, showing manufacturers’ optimism has risen to unprecedented heights amid the legislative progress made on tax reform. With 94.6% of respondents saying ...

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Construction Index Remains Strong in November

1 DAY AGO

The Dodge Momentum Index surged again in November, climbing 13.9% to 149.5 from the revised October reading of 131.3. The Momentum Index is a monthly measure of the first (or initial) report for nonresidential building projects in planning, which have been shown to lead construction spending for non...

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Cobalt-base Alloy 6

materials_q_and_a_graphicQ: Is there a problem using cobalt-base Alloy 6 material in amine applications in refineries and gas treatment plants?

A: This is a very good question, and the answer may be somewhat surprising to many people.

The Materials Q&A column in the Winter 2006 issue of Valve Magazine covered erosion-corrosion issues that can occur when cobalt-base Alloy 6 is used for boiler feedwater service in power plants. To review, boiler feedwater is often treated with amine compounds to deoxygenate the water, which reduces the corrosion rates in the steel piping system. It has been theorized (but not proven) that the presence of the amine compounds somehow prevents the reformation of the oxide passive layer on the Alloy 6 after it has been removed by high-velocity flow impingement. What is not understood is why this only occurs in cobalt alloys and not in other materials (such as austenitic stainless steels) that also rely on an oxide passive layer for corrosion protection.

In refineries, amine compounds are used to absorb unwanted dissolved gases—primarily hydrogen sulfide (H2S)—from liquid hydrocarbons. In natural gas treatment plants, the amine compounds are used to absorb H2S and carbon dioxide (CO2). This process is usually called “sweetening.” The most commonly-used compounds in these applications are the alkanolamines—monoethanolamine (MEA), diethanolamine (DEA) and methyldiethanolamine (MDEA).

The gaseous or liquid hydrocarbon is passed up through an absorber, and the amine fluid is passed in a counterflow direction (i.e., down) through the absorber. The unwanted H2S (and CO2 in the case of natural gas) are absorbed by the amine solution, which results in what is called “rich amine.”

In common systems, the rich amine exits the bottom of the absorber and passes through a rich amine letdown valve, where the pressure drop causes the gases to come out of solution.

Commonly, an amine regenerator valve is present that eventually takes a second pressure drop going into the regenerator. Some outgassing also occurs at this valve, but not to the same extent as is present in the rich amine letdown valve.

The regenerator produces what is called “lean” amine solution, which is then recirculated to the absorber.

Valves controlling the lean amine solution are not susceptible to sulfide stress cracking, and not especially susceptible to corrosion (because no H2S or CO2 is present). However, they do tend to be susceptible to cavitation because of the large pressure drops. These valves are usually supplied with anti-cavitation trim in standard hardened stainless-steel materials.

Valves controlling the rich amine are susceptible to both corrosion and sulfide stress cracking because of the H2S (and CO2 in gas treatment) and are susceptible to erosion damage because of the two-phase flow caused by the outgassing. Therefore, it would be favorable to be able to use a trim material in these valves that is known to be resistant to corrosion and sulfide stress cracking and resistant to erosion by the two-phase flow. Alloy 6 is famous for its resistance to various types of mechanical damage, including cavitation damage, flashing damage (which is similar to the two-phase gas-liquid erosion mechanism encountered here) and galling. It’s also commonly used in applications where sulfide stress cracking is a concern. The big question is, how well does Alloy 6 hold up against corrosion, given the fact that there are amines present in the fluid?

One might theorize that the Alloy 6 would suffer the same erosion-corrosion damage in the rich amine solution as it does in boiler feedwater applications. After all, the amines would scavenge oxygen from the water in the amine solution just as they do in boiler feedwater applications.

Deoxygenation does actually occur. In fact, the theory is this may be the reason for the successful use of 316 stainless steel in gas sweetening systems where temperatures and chloride levels would seem elevated enough to cause chloride stress corrosion cracking (SCC). It is known that as dissolved oxygen decreases, the tendency to suffer chloride SCC decreases. Elimination of dissolved oxygen may be the reason that SCC does not occur.

Despite the fact that theory would indicate a danger of erosion-corrosion for Alloy 6 in these applications, experience has indicated that this material actually works very well. There are literally thousands of control valves installed in rich amine letdown service and amine regenerator service that use Alloy 6 trim components. These valves include Alloy 6 in all the various product forms—solid cast components (UNS R30006), solid wrought components (UNS R30016) and hardface overlays (AWS CoCr-A), and they all work well in practice.

In other words, there is no reason to restrict the use of Alloy 6 trim materials in amine applications in refining and gas treatment systems. Save those restrictions for boiler feedwater applications.


Don Bush is principal materials engineer, Advanced Technology Group, Fisher Division, Emerson Process Management.

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