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From Cannon Balls to Pressure Seals: Graphite for Sealing

From Cannon Balls to Pressure Seals: Graphite for Sealing

From time to time, we re-publish well-re...

Gaskets Are Not Created Equal

Gaskets Are Not Created Equal

Gaskets are near the bottom of the food ...

Your Valves May Be Weaponized

Your Valves May Be Weaponized

The advent of the Internet of Things (Io...

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Industry Headlines

SVF Flow Controls Joins VMA

Friday, 22 June 2018  |  Chris Guy

This week SVF Flow Controls became a full member of the Valve Manufacturers Association (VMA). This is the fourth new VMA member in 2018 so far.

For over...

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Industry Headlines

SVF Flow Controls Joins VMA

5 HOURS AGO

This week SVF Flow Controls became a full member of the Valve Manufacturers Association (VMA). This is the fourth new VMA member in 2018 so far.

For over 35 years SVF Flow Controls of La Palma, CA has been manufacturing ball valves, actuators and controls for all industrial applications.

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Emerson Wins Global Tank Storage Award

1 DAY AGO

Emerson’s Rosemount 5900S 2-in-1 Radar Level Gauge has won the Outstanding Terminal Safety Technology Award at the 2018 Global Tank Storage Awards. This award is given to a product or technology that adds an additional layer of safety to the terminal and reduces risk to employees and the surroun...

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U.S. Specialty Chemicals Markets Continue to Gain

1 DAY AGO

The American Chemistry Council (ACC) reported that U.S. specialty chemicals market volumes continued to gain during the second quarter, increasing 0.5% in May after an upwardly revised 1% gain in April and a 0.4% gain in March. All changes in the data are reported on a three-month moving average (3M...

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Global LNG Trade Growing, Led by Australia and the U.S.

2 DAYS AGO

Global trade in liquefied natural gas (LNG) reached 38.2 billion cubic feet per day (Bcf/d) in 2017, a 10% (3.5 Bcf/d) increase from 2016 and the largest annual volume increase since 2010, according to the Annual Report on LNG trade by the International Association of Liquefied Natural Gas Importers...

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Optimism an All-Time High in NAM Survey

1 DAY AGO

In the latest Manufacturers’ Outlook Survey from the National Association of Manufacturers (NAM), it’s clear that businesses continue to experience highly elevated levels of activity as a result of policies like tax reform, with optimism once again breaking records —95.1% of responde...

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Texas Economy Continues to Expand at “Solid Pace”

2 DAYS AGO

The Texas economy is expanding at a solid pace. Employment has grown at a 3.6% annualized rate through May, driven by job gains in the goods-producing sector. Unemployment remains near its historical low, and labor markets are tight. The Dallas Fed’s Texas Business Outlook Surveys (TBOS) suggest...

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Specifying Valves for Hydrogen Service

materials_q_and_a_graphicQ: When specifying valves for hydrogen service, what are some of the material considerations I should keep in mind?

A: Hydrogen can cause a number of different adverse effects in metallic materials. The specific problems that can occur, and the methods for avoiding them, depend upon the service conditions. Although the subject is much too vast to cover completely in this column, following are descriptions of the predominant hydrogen damage mechanisms, along with some suggestions for avoiding problems.

Hydrogen Embrittlement
Hydrogen embrittlement, also called hydrogen stress cracking or hydrogen induced cracking, is a condition of low ductility in metals resulting from the absorption of hydrogen. Hydrogen embrittlement is mainly a problem in steels with ultimate tensile strength greater than 90 ksi, although a number of additional alloys are susceptible. Most hydrogen embrittlement failures occur as a result of absorption of hydrogen that is generated during plating, pickling, or cleaning operations. However, hydrogen charging may also occur in-service. This usually occurs in cases where hydrogen is generated due to corrosion, although it can also occur in high-temperature hydrogen applications. Hydrogen embrittlement failures are most often characterized as delayed, catastrophic failures occurring at temperatures near ambient, at stresses below the yield strength, and exhibiting single, non-branching cracks. However, failures deviating from these characteristics can and do occur.

The hydrogen embrittlement phenomenon requires a source of hydrogen ions (H+) or monatomic hydrogen (H). Diatomic (molecular) hydrogen (H2) will not cause hydrogen embrittlement, because the H2 molecules are too large to diffuse into the metallic crystal structure.

Hydrogen ions are created during any electrolytic or aqueous corrosion process, including general corrosion, galvanic corrosion, pitting corrosion, electrocleaning, electropolishing, pickling, and electroplating processes.

Monatomic hydrogen (H) is formed by dissociation of diatomic hydrogen (H2) at high temperatures. Reportedly, this dissociation begins to occur at around 350°F(175°C), with the proportion of H/H2 increasing as temperature increases.

It should be mentioned that although hydrogen embrittlement is most likely to occur at ambient temperatures, ambient-temperature failure may occur in a material that was "charged" with hydrogen during exposure at elevated temperature.

Since sulfide stress cracking is essentially hydrogen embrittlement catalyzed by the presence of sulfide ions, NACE MR0175/ISO 15156, Petroleum and Natural Gas Industries - Materials for Use in H2S-containing Environments in Oil and Gas Production, and/or NACE MR0103, Materials Resistant to Sulfide Stress Cracking in Corrosive Petroleum Refining Environments, can be used as guidelines for general materials selection to avoid hydrogen embrittlement. However, the requirements in these standards are somewhat conservative for avoidance of conventional hydrogen embrittlement. In general, steels below approximately 35 HRC are generally acceptable for applications where conventional hydrogen embrittlement is a concern, whereas the NACE standards would require steels to meet a 22 HRC maximum hardness requirement. Austenitic stainless steels, most nickel and copper alloys, and aluminum alloys are generally resistant to hydrogen embrittlement, although certain precipitation-hardened and/or strain-hardened grades in these material families can suffer hydrogen embrittlement.

Hydrogen Attack
When carbon and low-alloy steels are exposed to high-pressure, high-temperature hydrogen, the monatomic hydrogen can diffuse into the steel and combine with the carbon in the steel to form methane gas, which becomes trapped at grain boundaries and other discontinuities in the material. The resulting internal decarburization and grain boundary fissuring degrades the mechanical properties of the material. Resistance to hydrogen attack increases with increasing chromium and molybdenum levels, since these elements form more stable carbides than iron, and do not release the carbon to the hydrogen as readily. API-recommended Practice 941, Steels for Hydrogen Service at Elevated Temperatures and Pressure in Petroleum Refineries and Petrochemical Plants, includes a diagram (commonly called a Nelson curve), which shows zones where the carbon and alloy steel materials are acceptable as a function of hydrogen partial pressure and temperature.

Hydrogen Blistering
Hydrogen blistering is the formation of blisters containing hydrogen gas in steels. This occurs when monatomic hydrogen (H) diffuses through the steel and recombines into molecular hydrogen (H2) at internal defects such as voids, laminations, and non-metallic inclusions. Molecular hydrogen cannot diffuse back out through steel, so the gradual buildup of molecular hydrogen results in increased pressure inside the defect cavities, eventually causing blistering of the material. Killed steels often are specified for elevated-temperature hydrogen applications or for applications where it is known that ionic hydrogen is generated. Killed steels are steels treated with a strong deoxidizing agent such as silicon or aluminum in order to reduce the oxygen content in the molten ingot, which in turn reduces the level of gas porosity in the finished steel. Killed steels are more resistant to hydrogen blistering than non-killed steels due to their relative lack of internal voids. The term "killed" actually only pertains to wrought products; however, cast steels are also deoxidized with elements such as silicon or aluminum to prevent the formation of gas porosity.

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