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Industry and Regulatory Changes in Offshore Operations

Industry and Regulatory Changes in Offshore Operations

On May 13, 2016, the offshore oil and ga...

Strategies for Successful SIS Valve Diagnostic Implementation

Strategies for Successful SIS Valve Diagnostic Implementation

End users and contractors alike strive t...

Stop Check Valves

Stop Check Valves

Stop check valves are vital to several i...

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Industry Headlines

Weir Opens New Safety Relief Valve Facility in Malaysia

14 HOURS AGO

Weir has opened a new facility to increase the global reach and competitiveness of Weir valves by establishing a manufacturing and assembly plant close to Malaysia’s capital Kuala Lumpur.

The Malaysian operation has already successfully supplied several large and strategic projects, especially ...

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ValvTechnologies Names Garcia, Mermelstein to New Positions

5 DAYS AGO
ValvTechnologies Names Garcia, Mermelstein to New Positions

ValvTechnologies, Inc. has named David Garcia director of manufacturing and Steve Mermelstein as regional director, Americas and director, channel management.

Previously, West Point graduate Garcia served as director of operations for Merla Wellhead Solutions and held plant manager positions at Hallib...

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U.S. Still Top Producer of Petroleum, Natural Gas Hydrocarbons

4 DAYS AGO

The U.S. remained the world's top producer of petroleum and natural gas hydrocarbons in 2015, according to U.S. Energy Information Administration estimates . U.S. petroleum and natural gas production first surpassed Russia in 2012, and the U.S. has been the world's top producer of natural gas since 20...

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Why $50/Barrel Oil Means Stability to U.S. Producers

4 DAYS AGO

The rise to $50-per-barrel oil means a return to stability, particularly for domestic shale producers, according to Dan K. Eberhart, CEO, Canary, LLC. At this level , companies that saw the value of their product drop more than 75% in less than two years might have the confidence to resume drilling ac...

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Survey: Manufacturing Execs Investing in Advanced Tech

4 DAYS AGO

 A convergence of disruptive factors such as new technologies, increasing competition, and pricing pressures, is forcing manufacturers to increase investment in new products and services as they seek to innovate manufacturing capabilities, according to the 2016 KPMG Global Manufacturing Outlook ...

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Durable Goods Orders Surge 3.4%, But Demand Soft

4 DAYS AGO

New orders for manufactured durable goods in April increased $7.7 billion or 3.4% to $235.9 billion, the U.S. Census Bureau announced today. This increase, up three of the last four months, followed a 1.9% March increase. Excluding transportation, new orders increased 0.4%. Excluding defense, new or...

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Multi-colored Stain on Valves

materials_q_and_a_graphicQ: I am handling high purity-water and keep getting a multi-colored stain on my valves and other equipment. What is this, and how can I prevent it?

A: You are describing a phenomenon called "rouging," a term that pertains to the multi-colored stain you are seeing. Rouging is a problem that is seen primarily in high-purity water applications or steam. Though more commonly associated with the pharmaceutical and electronics industries, it can occur most anywhere. At the lower temperatures rouge is red or yellowish in appearance, but in high-temperature steam it will be dark gray or black. The FDA has not made any formal opinion about rouging, but pharmaceutical companies are concerned about contamination of their products so they go to great lengths to prevent it and to clean their systems when it occurs-incurring undesired downtime and expense.

The mechanism of rouging is still not fully understood and as a result there are some myths and misconceptions about what it is and how to prevent it. Essentially, rouge is a form of rust, i.e., iron oxide, but different than the heavy rust seen when stainless steel is not cleaned properly after heat treatment or welding. While normal rust is a result of improper cleaning during manufacture, rouge is a much thinner layer that occurs when perfectly cleaned stainless steel reacts with high-purity water environments. Rouge seems to be more prevalent at temperatures in excess or 60° C.

We know that stainless steels achieve their corrosion resistance by developing a very thin microscopic chromium oxide layer. The general consensus about rouging is that certain services, such as high purity water with very low oxygen content, dissolve this protective layer and allow the stainless steel to resume corroding. This corrosion is then responsible for the staining we call rouging. These stains have been analyzed as being various types of iron oxide as well as containing traces of chromium and nickel.

While mainly an aesthetics problem, most people still want to prevent rouge in their systems. One commonly held belief is that the ferrite phase in cast stainless steels or welds causes rouging, and purchasers of valves and other equipment frequently impose strict limits on the ferrite content of cast stainless steels. Since wrought stainless steels with no ferrite also experience rouging, it doesn't appear that ferrite is the culprit.

A study conducted by AvestaPolarit1, found that the water's gas content and a metal's surface finish were influential for rouging. Basically, water with high oxygen and low carbon dioxide content was less likely to cause rouging as were electro-polished surfaces of the metal components. This study also found no significant correlation for the different alloy grades, including duplex stainless steels with their high ferrite content.

Since most people find rouge objectionable in their systems, much attention has been given to its removal. Various acids and chelates are used to clean systems of rouge, but these can leave behind their own contaminates or films. In addition, if acid exposure is not controlled closely, the acid can etch the metal surfaces thus destroying the expensive electro-polished surfaces. Therefore, the most effective way to prevent rouge is by somehow introducing sufficient oxygen to the system, which helps maintain the protective chromium oxide layer.

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