01172018Wed
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Young Valve Professionals: Logan Moore

Young Valve Professionals: Logan Moore

In 2014, VMA's leadership created the Va...

VALVE Magazine: Readers' Choice 2017

VALVE Magazine: Readers' Choice 2017

Happy New Year to our VALVE Magazine rea...

Educational Opportunities Abound at New VMA Knowledge Forum

Educational Opportunities Abound at New VMA Knowledge Forum

From technical to manufacturing to human...

Offshore Production in a Low Oil-Price Environment

Offshore Production in a Low Oil-Price Environment

Three years ago, The Washington Post publi...

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Interior Coatings for Waterworks Valves

Interior Coatings for Waterworks Valves

Monday, 15 January 2018  |  John V. Ballun, P. E.

Since the 1990s, two types of epoxy coatings have been commonly specified and used for iron valves in the waterworks industry: fusion-bonded epoxy and...

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Industry Headlines

ASCO Valve and Numatics Now Doing Business as ASCO, L.P.

1 DAY AGO

Effective January 1, 2018, ASCO Valve, Inc. and Numatics, Inc. began doing business as ASCO, L.P. This change in legal entities affects neither current channel alignment nor purchasing processes—everything will remain the same, including product authorizations. Within ASCO, a business unit of Em...

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Union Tech Names Chris Mayo Director for Global Power

1 DAY AGO

Union Tech recently announced that Chris Mayo has joined the valve sales team as director for global power. He will be primarily responsible for power markets, which include Union Tech’s Z1 Unibody Power Valve amongst other valve products in the Z-Series line.

Mayo is an industry veteran who bri...

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Natural Gas Prices, Production, Exports Increased in 2017

3 HOURS AGO

Overall, natural gas prices at key regional trading hubs were less volatile in 2017 than in previous years, as pipelines that came online throughout the year eased some infrastructure constraints that affect regional prices, according to the U.S. Energy Information Administration . In the Northeast, w...

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Pipeline Capacity Expansions Accelerating in U.S. Northeast

2 DAYS AGO

With projects such as Columbia Gas Transmission’s Leach Xpress and Energy Transfer Partners’ Rover pipeline, “[t]he U.S. northeast should realize an increase of more than 3 Bcf/d of natural gas pipeline capacity by the end of this quarter, compared with an increase of 2.3 Bcf/d in ...

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House Unanimously Passes Miscellaneous Tariff Bill

1 HOUR AGO

The House of Representatives voted unanimously this week to pass H.R. 4318 , the Miscellaneous Tariff Bill (MTB) Act of 2018. This bipartisan, bicameral legislation was written to increase the competitiveness of American manufacturers by temporarily reducing tariffs on nearly 1,700 different products ...

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Manufacturing Technology Orders Increased in November

1 DAY AGO

Orders for manufacturing technology climbed year over year and year to date in November 2017 according to the Association for Manufacturing Technology (AMT). Orders totaled $425.97 million for the month, up 19.0% compared to November 2016. At a cumulative total of $4.06 billion for the year, orders we...

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Multi-colored Stain on Valves

materials_q_and_a_graphicQ: I am handling high purity-water and keep getting a multi-colored stain on my valves and other equipment. What is this, and how can I prevent it?

A: You are describing a phenomenon called "rouging," a term that pertains to the multi-colored stain you are seeing. Rouging is a problem that is seen primarily in high-purity water applications or steam. Though more commonly associated with the pharmaceutical and electronics industries, it can occur most anywhere. At the lower temperatures rouge is red or yellowish in appearance, but in high-temperature steam it will be dark gray or black. The FDA has not made any formal opinion about rouging, but pharmaceutical companies are concerned about contamination of their products so they go to great lengths to prevent it and to clean their systems when it occurs-incurring undesired downtime and expense.

The mechanism of rouging is still not fully understood and as a result there are some myths and misconceptions about what it is and how to prevent it. Essentially, rouge is a form of rust, i.e., iron oxide, but different than the heavy rust seen when stainless steel is not cleaned properly after heat treatment or welding. While normal rust is a result of improper cleaning during manufacture, rouge is a much thinner layer that occurs when perfectly cleaned stainless steel reacts with high-purity water environments. Rouge seems to be more prevalent at temperatures in excess or 60° C.

We know that stainless steels achieve their corrosion resistance by developing a very thin microscopic chromium oxide layer. The general consensus about rouging is that certain services, such as high purity water with very low oxygen content, dissolve this protective layer and allow the stainless steel to resume corroding. This corrosion is then responsible for the staining we call rouging. These stains have been analyzed as being various types of iron oxide as well as containing traces of chromium and nickel.

While mainly an aesthetics problem, most people still want to prevent rouge in their systems. One commonly held belief is that the ferrite phase in cast stainless steels or welds causes rouging, and purchasers of valves and other equipment frequently impose strict limits on the ferrite content of cast stainless steels. Since wrought stainless steels with no ferrite also experience rouging, it doesn't appear that ferrite is the culprit.

A study conducted by AvestaPolarit1, found that the water's gas content and a metal's surface finish were influential for rouging. Basically, water with high oxygen and low carbon dioxide content was less likely to cause rouging as were electro-polished surfaces of the metal components. This study also found no significant correlation for the different alloy grades, including duplex stainless steels with their high ferrite content.

Since most people find rouge objectionable in their systems, much attention has been given to its removal. Various acids and chelates are used to clean systems of rouge, but these can leave behind their own contaminates or films. In addition, if acid exposure is not controlled closely, the acid can etch the metal surfaces thus destroying the expensive electro-polished surfaces. Therefore, the most effective way to prevent rouge is by somehow introducing sufficient oxygen to the system, which helps maintain the protective chromium oxide layer.

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