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Valve Selection in Pulp and Paper Operations

Valve Selection in Pulp and Paper Operations

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VMA Technical Event: Engineering Valves in the Extreme

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Industry Headlines

Kansas City Fed Shows Manufacturing At 6-Year High

Friday, 24 March 2017  |  Chris Guy

Tenth District manufacturing activity strengthened further in March, and many indexes of expectations for future activity were at or near record highs...

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Industry Headlines

GE Oil & Gas Expands with New Sub Saharan Africa Facility

1 DAY AGO

GE Oil & Gas opened a new facility in Takoradi Port, Ghana, expanding its global footprint and supporting local investment. The facility, which will be the primary service center for deep-water offshore projects in Ghana, has a 1,600 square meter indoor test area with capability for testing thre...

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Metso Launches Digital Program to Accelerate Growth

2 DAYS AGO

Metso has set up a Digital Program to accelerate the company’s digital capabilities, which are required to succeed in the future of minerals processing and flow control. Metso's ambition is to become one of the digital leaders in the industries it serves. This means for example turning custome...

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Shell Looking to Lower Cost of Offshore Projects

1 DAY AGO

“With oil prices hovering around $50 a barrel or less, and a rising amount of renewable energy chipping away at market share, Shell is going lean on its deepwater projects to make sure it can eke out a profit from all of its operations,” writes ChemInfo .

For example, Shell is attempting to ...

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Report Says PA Can Support Four More Ethane Crackers

1 DAY AGO

A new report from IHS Markit, commissioned by the state of Pennsylvania, forecasts $2.7 to 3.7 billion in investments in natural gas liquid (NGL) assets as well as the opportunity to attract additional cracker plants, and petrochemical and plastics manufacturing. IHS Markit believes the Marcellus an...

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Kansas City Fed Shows Manufacturing At 6-Year High

20 HOURS AGO

Tenth District manufacturing activity strengthened further in March, and many indexes of expectations for future activity were at or near record highs. Most price indexes increased moderately. The month-over-month composite index was 20 in March , its highest reading since March 2011, up from 14 in Fe...

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Consumer Sentiment Reaches Highest Level Since 2000

4 DAYS AGO

The overall level of consumer sentiment remained quite favorable in early March due to renewed strength in current economic conditions as well as the extraordinary influence of partisanship on economic prospects. The current economic conditions component reached its highest level since 2000, largely...

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Materials Selection for Deepwater Gate Valves

spr11_deepsea_fig1Figure 1. A typical subsea installation showing valves, manifolds and jumpers

With the discovery of oil and gas in water depths thousands of feet below the surface, selection of valves is more important, difficult and complicated. Gate valves, which are often used in subsea applications, are available today in a wide selection of materials, but choosing them requires knowledge of new challenges and established standards.

In years past, the materials used to handle corrosive service in the sea faced mainly the challenges of hydrogen sulfide (H2S), carbon dioxide (CO2) and chlorides. With deepwater well drilling, the newer subsea systems being drilled also need to handle chemicals that will minimize paraffin, asphaltene, hydrates and scale formation as well as provide corrosion inhibitions. These chemicals, however, have adverse effects on metallic and non-metallic materials, and the problem is compounded when materials have to handle produced fluids, annular fluids and the injected chemicals. Also, with subsea systems, the effects of hydrogen embrittlement from the cathodic protection system have to be taken into account. For this reason, choosing the materials to be used in gate valves for subsea is especially challenging.

WHAT GOES INTO THE CHOICE

In selection of materials for subsea gate valves, the following must be considered:

  • Composition of produced fluids in contact with valves and internal parts—all wetted parts
  • Service temperatures
  • Operating pressure ranges
  • Galvanic effects from contact of dissimilar materials
  • Crevice corrosion at seal and flange faces
  • Temperature and chemical resistance for non-metallic materials
  • Cathodic protection (CP) on materials
  • Effectiveness of coatings on materials
  • Weldability for weld overlay
  • Material availability and cost
  • Compatibility of materials with injected fluids

 


VALVE BODY MATERIALS

Several organizations provide recommendations for the selection of materials for valves. These include the National Association for Corrosion Engineers (NACE) and American Petroleum Institute (API).

NACE only covers metallic material requirements for resistance to sulfide stress cracking (SCC) for oilfield equipment, which is not intended to include design specification. (Other forms of corrosion and other modes of failure are outside the scope of NACE’s standard and should be considered in design and operation of equipment.) NACE also has requirements for low-alloy materials exposed to sour service. For example, the organization requires that hardness for alloy materials be limited to HRC 22 maximum. Nickel content is limited to 1% maximum, and NACE also has proposed heat treatment such as normalized, normalized and temper, and quench and temper.

API has several standards, such a specification 17D “Specification for Subsea Wellhead and Christmas Tree Equipment,” which uses the material requirements of API 6A.

Specification API 6A covers a number of specific areas for subsea valves, including strength, impact and quality testing. Strength level depends on the pressure rating of the equipment. For example, for flanged end connections, equipment used to pressure levels of 10,000 psi must be manufactured from material having a minimum yield strength of 60,000 psi. Equipment exceeding 10,000 psi pressure must be designed using equipment with specified yield strength of 75,000 psi (refer to API 6A Table 5.2).

Once the fluids that will be produced have been determined, valve selection can occur. Besides the challenges the fluids will produce, as well as the temperatures and pressures involved, the service conditions must also be considered. This includes how long the equipment might be exposed to seawater. Alloy steel will handle most benign conditions, including low CO2 for short periods of time, but even short seawater exposure can cause corrosion of critical components. This is especially true if seawater is trapped in those components and cannot be flushed out in a timely manner. Even with benign conditions, there is need for long-term life—in many cases over 25 years.

Valves as specified using API and NACE standards to handle strength and corrosive requirements can be grouped as follows with typical materials and applicable service conditions:


Stainless-steel Valves
spr11_deepsea_fig2Figure 2. Typical subsea tree assembly

When environments call for stainless steels such as 410 and F6NM, they may have similar corrosion resistance in oilfield environments; however, they have significant differences in weldability. Stainless 410 in the wrought and welded condition has lower impact toughness than F6NM. Welds of 410 have lower toughness, and depending on the operation, F6NM is often used if there is a risk of Joule Thomson effect (the temperature change of a gas or liquid forced through a valve or porous plug while kept insulated so that no heat is exchanged with the environment) at the wellhead. Even though stainless steels such as 410 and F6NM have good corrosion resistance and can handle mild corrosive conditions, weld overlay of critical sealing surfaces with corrosion-resistant alloy (CRA) is used to minimize pitting.


Duplex Stainless-steel Components

Although duplex stainless steels have good corrosion resistance in most environments, the use of these materials is limited for wellhead equipment because of the danger associated with sigma formation during heat treatment in large section thicknesses. Improper heat treatment not only results in poor corrosion resistance, but also poor toughness property. Duplex stainless steels require a satisfactory balance between ferrite and austenite both in the wrought and welded structures. Super duplex is specified where the Pitting Resistance Index (PRE) exceeds 40, whereas duplex is specified for thin components.

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