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Basics of Elastomeric Seal Design

Basics of Elastomeric Seal Design

Engineers need critical design informati...

Wastewater Treatment

Wastewater Treatment

Society’s desire for a clean envir...

Controlling Our Water Systems, Part II

Controlling Our Water Systems, Part II

To better understand the actuators and c...

Controlling Our Water Systems

Controlling Our Water Systems

Actuators and controls are a critical pr...

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Industry Headlines

Sharpest Rise in U.S. Manufacturing Production Since November

Monday, 25 July 2016  |  Chris Guy

July data signaled a further rebound in business conditions across the U.S. manufacturing sector, led by a robust expansion of incoming new work and t...

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Industry Headlines

Emerson Exploring Acquisition of Pentair Valves & Controls

10 HOURS AGO

Reuters UK has spoken to sources that confirm Emerson has made an offer to acquire Pentair Valves & Controls. Pentair Plc added the Valves & Controls division after its merger with Tyco Flow Control in 2012.

“Pentair has received offers for the valves and controls business from companies o...

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Pentair Valves & Controls Rolls Out Customer Education Program

4 DAYS AGO

Pentair Valves & Controls has introduced the Pentair University customer education program for past, present and prospective clients and industry leaders in various locations throughout the world. Pentair University’s invitation-only seminars are free to attend. In some regions of the worl...

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Canadian Oil & Gas Earnings Signal Industry Recovery

3 DAYS AGO

The Canadian oil and gas earnings season began yesterday with “signs of an industry recovery as Encana Corp and Precision Drilling Corp outlined plans to boost activity,” Reuters reports .

Analysts say “the uptick in optimism might be mirrored by some U.S. shale companies like Pioneer ...

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U.S. Lower 48 Sustains $150B in Cuts by Upstream Developers

4 DAYS AGO

Out of the more than $370 billion in global capital expenditure cut by upstream developers across 2016 and 2017, $150 billion was slashed in the U.S. Lower 48 alone — more than three times any other single country. Largely due to responsiveness and flexibility in the unconventional space, spen...

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Sharpest Rise in U.S. Manufacturing Production Since November

10 HOURS AGO

July data signaled a further rebound in business conditions across the U.S. manufacturing sector, led by a robust expansion of incoming new work and the fastest upturn in production volumes for eight months. Job creation also strengthened in July, with the latest increase in payroll numbers the fast...

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Texas Manufacturing Activity Stabilizes

10 HOURS AGO

Texas factory activity held steady in July, according to business executives responding to the Texas Manufacturing Outlook Survey . The production index, a key measure of state manufacturing conditions, came in near zero after two months of negative readings, suggesting output stopped falling this mon...

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Materials Selection for Deepwater Gate Valves

spr11_deepsea_fig1Figure 1. A typical subsea installation showing valves, manifolds and jumpers

With the discovery of oil and gas in water depths thousands of feet below the surface, selection of valves is more important, difficult and complicated. Gate valves, which are often used in subsea applications, are available today in a wide selection of materials, but choosing them requires knowledge of new challenges and established standards.

In years past, the materials used to handle corrosive service in the sea faced mainly the challenges of hydrogen sulfide (H2S), carbon dioxide (CO2) and chlorides. With deepwater well drilling, the newer subsea systems being drilled also need to handle chemicals that will minimize paraffin, asphaltene, hydrates and scale formation as well as provide corrosion inhibitions. These chemicals, however, have adverse effects on metallic and non-metallic materials, and the problem is compounded when materials have to handle produced fluids, annular fluids and the injected chemicals. Also, with subsea systems, the effects of hydrogen embrittlement from the cathodic protection system have to be taken into account. For this reason, choosing the materials to be used in gate valves for subsea is especially challenging.

WHAT GOES INTO THE CHOICE

In selection of materials for subsea gate valves, the following must be considered:

  • Composition of produced fluids in contact with valves and internal parts—all wetted parts
  • Service temperatures
  • Operating pressure ranges
  • Galvanic effects from contact of dissimilar materials
  • Crevice corrosion at seal and flange faces
  • Temperature and chemical resistance for non-metallic materials
  • Cathodic protection (CP) on materials
  • Effectiveness of coatings on materials
  • Weldability for weld overlay
  • Material availability and cost
  • Compatibility of materials with injected fluids

 


VALVE BODY MATERIALS

Several organizations provide recommendations for the selection of materials for valves. These include the National Association for Corrosion Engineers (NACE) and American Petroleum Institute (API).

NACE only covers metallic material requirements for resistance to sulfide stress cracking (SCC) for oilfield equipment, which is not intended to include design specification. (Other forms of corrosion and other modes of failure are outside the scope of NACE’s standard and should be considered in design and operation of equipment.) NACE also has requirements for low-alloy materials exposed to sour service. For example, the organization requires that hardness for alloy materials be limited to HRC 22 maximum. Nickel content is limited to 1% maximum, and NACE also has proposed heat treatment such as normalized, normalized and temper, and quench and temper.

API has several standards, such a specification 17D “Specification for Subsea Wellhead and Christmas Tree Equipment,” which uses the material requirements of API 6A.

Specification API 6A covers a number of specific areas for subsea valves, including strength, impact and quality testing. Strength level depends on the pressure rating of the equipment. For example, for flanged end connections, equipment used to pressure levels of 10,000 psi must be manufactured from material having a minimum yield strength of 60,000 psi. Equipment exceeding 10,000 psi pressure must be designed using equipment with specified yield strength of 75,000 psi (refer to API 6A Table 5.2).

Once the fluids that will be produced have been determined, valve selection can occur. Besides the challenges the fluids will produce, as well as the temperatures and pressures involved, the service conditions must also be considered. This includes how long the equipment might be exposed to seawater. Alloy steel will handle most benign conditions, including low CO2 for short periods of time, but even short seawater exposure can cause corrosion of critical components. This is especially true if seawater is trapped in those components and cannot be flushed out in a timely manner. Even with benign conditions, there is need for long-term life—in many cases over 25 years.

Valves as specified using API and NACE standards to handle strength and corrosive requirements can be grouped as follows with typical materials and applicable service conditions:


Stainless-steel Valves
spr11_deepsea_fig2Figure 2. Typical subsea tree assembly

When environments call for stainless steels such as 410 and F6NM, they may have similar corrosion resistance in oilfield environments; however, they have significant differences in weldability. Stainless 410 in the wrought and welded condition has lower impact toughness than F6NM. Welds of 410 have lower toughness, and depending on the operation, F6NM is often used if there is a risk of Joule Thomson effect (the temperature change of a gas or liquid forced through a valve or porous plug while kept insulated so that no heat is exchanged with the environment) at the wellhead. Even though stainless steels such as 410 and F6NM have good corrosion resistance and can handle mild corrosive conditions, weld overlay of critical sealing surfaces with corrosion-resistant alloy (CRA) is used to minimize pitting.


Duplex Stainless-steel Components

Although duplex stainless steels have good corrosion resistance in most environments, the use of these materials is limited for wellhead equipment because of the danger associated with sigma formation during heat treatment in large section thicknesses. Improper heat treatment not only results in poor corrosion resistance, but also poor toughness property. Duplex stainless steels require a satisfactory balance between ferrite and austenite both in the wrought and welded structures. Super duplex is specified where the Pitting Resistance Index (PRE) exceeds 40, whereas duplex is specified for thin components.

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